Publication

Chikyukagaku(Geochemistry) 52, 4, 171-210 (2018)
Genesis of REY-rich mud: A new perspective based on independent component analysis

Author

Yasukawa, K., Nakamura, K., Fujinaga, K., Iwamori, H. and Kato, Y.

Abstract

Since the discovery of rare-earth elements and yttrium (REY)-rich mud in the Pacific Ocean, a variety of research has been conducted to understand its spatial distribution and genesis. In this paper, we review the latest research outcomes on REY-rich mud, including the discovery of “extremely REY-rich mud” containing >5,000 ppm of total REY, a promising deep-sea mineral resource in Japan’s exclusive economic zone surrounding Minamitorishima Island. Then, we introduce a new statistical approach based on independent component analysis (ICA) to clarify the origin of REY-rich mud in the Pacific and Indian oceans, with a theoretical background and a protocol of ICA application on geochemical data. Independent components extracted from a multi-elemental dataset of ~4,000 samples demonstrate distinctive geochemical features, and their spatiotemporal distributions indicate that the sedimentation rate is an underlying key factor for REY-enrichment. We also refer to an important link between the genesis of REY-rich mud and Earth system dynamics. Finally, we focus on some challenges to be overcome. One of the most significant questions concerns the formation mechanism of the extremely REY-rich mud. An important key to this question is the depositional age of the extraordinary sediment layer.